Do not allow to enter sewers/ surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralising agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
Specific end use(s) No further relevant information available.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
Acetic Acid Glacial
10ppm
25mg/m³
15ppm
37mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Wear protective clothing.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
9. Physical and Chemical Properties
General information
Appearance
Clear liquid
Odour
Pungent
pH
5
Vapour Pressure
11.4hPa
Density
Not determined.
Boiling Point
118°C
Melting Point
Undetermined
Solubility
Fully miscible.
Specific Gravity of Density
Not available.
Flash Point
43 °C (109.4 °F)
Flammable (Explosive) Limits
Lower: 4.0 Vol%
Upper: 19.0 Vol%
Ignition Temperature
Product is not selfigniting.
Formula
Not available.
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
64-19-7 Acetic Acid Glacial
Oral LD50 3310 mg/kg (rat)
Dermal LD50 1060 mg/kg (rabbit)
Eye contact
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Skin contact
Strong caustic effect on skin and mucous membranes.
Ingestion
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach.
Inhalation
No sensitising effects known.
Toxicity and irritation
The product shows the following dangers according to internally approved calculation methods for preparations:
Corrosive
Irritant
Very toxic
Danger through skin absorption.
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
Interactive effects No interactive effects between components are known.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety Health Administration)
None of the ingredients is listed.
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 1: slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
13. Disposal Considerations
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
14. Transport Information
ADG label required
Class 6.1 ToxicClass 8 Corrosive
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
UN Number
UN2790
Proper shipping name
2790 ACETIC ACID SOLUTION mixture
Transport hazard class
Class 8 Corrosive substances.
Packing group
II
Environmental hazard
No
Special precautions for users
Warning: Corrosive substances.
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups: Acids
Additional information
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category: 2
Tunnel restriction code: E
15. Regulatory Information
Poisons Schedule Number
64-19-7 Acetic Acid Glacial S2, S5, S6
Other Information
A Chemical Safety Assessment has not been carried out.
16. Other Information
SDS preparation date
15 May 2026
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific features and shall not establish a legally valid contractual relationship.