Acid Alcohol 1% Solution

1. Identification

Product Identifiers

Product Name

Acid Alcohol 1% Solution

Other Names

Nil

Product Number(s)

26370-05, 26396-13, 26753-02, 26754-03, EMS26396-13

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

• Highly flammable liquid and vapour.
• May cause cancer.
• May cause damage to the central nervous system and the visual organs.
• May be corrosive to metals.

Precautionary Statement(s)

• Obtain special instructions before use.
• Do not handle until all safety precautions have been read and understood.
• Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• Keep container tightly closed.
• Ground / bond container and receiving equipment.
• Use explosion-proof [electrical/ventilating/lighting] equipment.
• Use non-sparking tools.
• Take action to prevent static discharge.
• Do not breathe dust/fume/gas/mist/vapours/spray.
• Wash thoroughly after handling.
• Do not eat, drink or smoke when using this product.
• Wear protective gloves/protective clothing/eye protection/face protection/hearing protection

Primary route(s) of entry

Human Health

Eyes

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. IF exposed or concerned: Call a POISONCENTER/ doctor.

Skin

Take off immediately all contaminated clothing. Rinse skin with water.

Environment

3. Composition / Information on Ingredients

4. First Aid Measures

Ingestion

Rinse mouth. Do not induce vomiting. Call a physician immediately

Inhalation

Remove person to fresh air and keep comfortable for breathing.

Skin Contact

Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a physician immediately

Eye Contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately.

Other Information

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

HAZCHEM

No further relevant information available.

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental precautions

• Dilute with plenty of water.
• Do not allow to enter sewers/ surface or ground water.

Methods and materials for containment and clean up

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
• Dispose contaminated material as waste according to section 13.
• Ensure adequate ventilation.

7. Handling and Storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.
• Prevent formation of aerosols.
• Information about protection against explosions and fires:
• Keep ignition sources away - Do not smoke.
• Protect from heat.
• Protect against electrostatic charges.

Conditions for safe storage

• Requirements to be met by storerooms and receptacles: Store in a cool location.
• Information about storage in one common storage facility: Not required.
• Further information about storage conditions:
• Keep receptacle tightly sealed.
• Store in cool, dry conditions in well sealed receptacles.
• Protect from heat and direct sunlight.
• Specific end use(s) No further relevant information available.

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

• No further data; see section 7.
• General Protective and Hygienic Measures
• Keep away from foodstuffs, beverages and feed.
• Immediately remove all soiled and contaminated clothing.
• Wash hands before breaks and at the end of work.
• Avoid contact with the skin.
• Avoid contact with the eyes and skin.

Personal protective equipment

Eye and face protection

Tightly sealed goggles

Skin protection

• Protective gloves
• The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
• Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
• Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
• Material of gloves
• The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
• Penetration time of glove material
• The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Body protection

No further information available

Respiratory protection

• In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
• respiratory protective device that is independent of circulating air.

9. Physical and Chemical Properties

General information

Appearance

Colourless Liquid

Odour

Characteristic

pH

1.1 - 1.4

Vapour Pressure

59 hPa (44.3 mm Hg) at 20 °C (68 °F)

Density

No data available

Boiling Point

No data available

Melting Point

No data available

Solubility

No data available

Specific Gravity of Density

0.79

Flash Point

13 °C (55.4 °F)

Flammable (Explosive) Limits

Not applicable.

Ignition Temperature

425 °C (797 °F)

10. Stability and Reactivity

Reactivity

Highly flammable liquid and vapour.

Chemical stability

Stable under normal conditions.

Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

Conditions to avoid

Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.

Incompatible materials

No additional information available

11. Toxicological Information

Acute effects

• LD/LC50 values that are relevant for classification:
• 64-17-5 Ethyl alcohol
• Oral LD50 7,060 mg/kg (rat)
• Inhalative LC50/4 h 20,000 mg/l (rat)

Eye contact

No irritating effect.

Skin contact

Irritant to skin and mucous membranes.

Ingestion

No sensitizing effects known.

Inhalation

No sensitizing effects known.

Toxicity and irritation

• The product shows the following dangers according to internally approved calculation methods for preparations:
• Harmful
• Irritant
• Interactive effects No interactive effects between components are known.

12. Ecological Information

Ecotoxicity

No further relevant information available

Persistence and degradability

No further relevant information available

Bioaccumulative potential

No further relevant information available

Other adverse effects

• General notes:
• Water hazard class 1 (Self-assessment): slightly hazardous for water
• Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

No further relevant information available.

UN Number

UN1133

Proper shipping name

• DOT Adhesives
• ADR 1133 ADHESIVES
• IMDG, IATA ADHESIVES

Transport hazard class

• DOT
• Class 3 Flammable liquids
• Label 3
• ADR, IMDG, IATA
• Class 3 Flammable liquids

Packing group

3

Environmental hazard

Not applicable

Special precautions for users

Not applicable

Additional information

• Transport/Additional information:
• DOT
• Quantity limitations On passenger aircraft/rail: 5 L
• On cargo aircraft only: 60 L
• ADR
• Excepted quantities (EQ) Code: E2
• Maximum net quantity per inner packaging: 30 mL
• Maximum net quantity per outer packaging: 500 mL
• IMDG
• Limited quantities (LQ) 5L
• Excepted quantities (EQ) Code: E2
• Maximum net quantity per inner packaging: 30 mL
• Maximum net quantity per outer packaging: 500 mL
• Special precautions for user Warning: Flammable liquids
• Hazard identification number (Kemler code): 33
• EMS Number: F-E,S-D
• Stowage Category B

15. Regulatory Information

Poisons Schedule Number

No further relevant information available.

Other Information

• Section 355 (extremely hazardous substances):
• 7647-01-0 hydrogen chloride
• Section 313 (Specific toxic chemical listings):
• 67-63-0 propan-2-ol
• 67-56-1 Methyl Alcohol
• 7647-01-0 hydrogen chloride
• TSCA (Toxic Substances Control Act):
• All components have the value ACTIVE.
• Hazardous Air Pollutants
• 67-56-1 Methyl Alcohol
• 7647-01-0 hydrogen chloride
• Proposition 65
• Chemicals known to cause cancer:
• None of the ingredients is listed.
• Chemicals known to cause reproductive toxicity for females:
• None of the ingredients is listed.
• Chemicals known to cause reproductive toxicity for males:
• None of the ingredients is listed.
• Chemicals known to cause developmental toxicity:
• 64-17-5 Ethyl alcohol
• 67-56-1 Methyl Alcohol
• Carcinogenic categories
• EPA (Environmental Protection Agency)
• None of the ingredients is listed.
• TLV (Threshold Limit Value)
• 64-17-5 Ethyl alcohol A3
• 67-63-0 propan-2-ol A4
• 7647-01-0 hydrogen chloride A4
• NIOSH-Ca (National Institute for Occupational Safety and Health)
• None of the ingredients is listed.

16. Other Information

SDS preparation date

17 February 2026

Comments

• Abbreviations and acronyms:
• ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
• Carriage of Dangerous Goods by Road)
• IMDG: International Maritime Code for Dangerous Goods
• DOT: US Department of Transportation
• IATA: International Air Transport Association
• EINECS: European Inventory of Existing Commercial Chemical Substances
• ELINCS: European List of Notified Chemical Substances
• CAS: Chemical Abstracts Service (division of the American Chemical Society)
• NFPA: National Fire Protection Association (USA)
• HMIS: Hazardous Materials Identification System (USA)
• VOC: Volatile Organic Compounds (USA, EU)
• LC50: Lethal concentration, 50 percent
• LD50: Lethal dose, 50 percent
• PBT: Persistent, Bioaccumulative and Toxic
• vPvB: very Persistent and very Bioaccumulative
• NIOSH: National Institute for Occupational Safety
• OSHA: Occupational Safety Health
• TLV: Threshold Limit Value
• PEL: Permissible Exposure Limit
• REL: Recommended Exposure Limit
• BEI: Biological Exposure Limit
• Flammable liquids 2: Flammable liquids - Category 2
• Carcinogenicity 1A: Carcinogenicity - Category 1A
• Specific target organ toxicity (single exposure) 2: Specific target organ toxicity (single exposure) - Category 2

References

EMS SDS Acid Alcohol 1% 28/04/2025 https://www.emsdiasum.com/docs/technical/msds/26370-05.pdf