Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion
Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Eyes
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. If eye irritation persists: Get medical advice/attention.
Skin
Wash with plenty of water. Take off immediately all contaminated clothing and wash it before reuse. If skin irritation persists: Get medical advice/attention.
Environment
Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
Methyl Methacrylate
80-62-6
≤2.5%
Substances
dibenzoyl peroxide
94-36-0
≤2.5%
Substances
4. First Aid Measures
Ingestion
If symptoms persist consult doctor.
Inhalation
Supply fresh air or oxygen; call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
Use fire extinguishing methods suitable to surrounding conditions.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
Mouth respiratory protective device.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Keep respiratory protective device available.
Conditions for safe storage
Keep container tightly sealed.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
Methyl Methacrylate
50ppm
208mg/m³
100ppm
416mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Wear protective clothing.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. Physical and Chemical Properties
General information
Appearance
Colourless powder
Odour
Odourless
pH
Not determined
Vapour Pressure
Not determined
Density
1.188 g/cm³
Boiling Point
Undetermined
Melting Point
150°C
Solubility
Not miscible or difficult to mix.
Specific Gravity of Density
Not available.
Flash Point
Not applicable
Flammable (Explosive) Limits
Not determined.
Ignition Temperature
304°C
Formula
Not available
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
Not available.
Eye contact
Irritating effect.
Skin contact
Irritant to skin and mucous membranes. Sensitisation possible through skin contact. Danger through skin adsorption.
Ingestion
Not available.
Inhalation
Not available.
Toxicity and irritation
Not available.
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 2: hazardous for water.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13. Disposal Considerations
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
A Chemical Safety Assessment has not been carried out.
16. Other Information
SDS preparation date
15 February 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.