Dispose of contents/container in accordance with local/regional/national/international regulations.
Primary route(s) of entry
Not Available
Human Health
Inhalation
Remove person to fresh air and keep comfortable for breathing
Ingestion
Rinse mouth. DO NOT induce vomiting.
Eyes
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison centre/doctor.
Skin
Take off immediately all contaminate clothing. Rinse skin under water/shower. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
Environment
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
Ethyl Alcohol
64-17-5
>50-≤100%
Mixture of substances with non-hazardous additions
Methyl Alcohol
67-56-1
≤2.5%
Mixture of substances with non-hazardous additions
Hydrogen Chloride
7647-01-0
≤2.5%
Mixture of substances with non-hazardous additions
Mixture of substances with non-hazardous additions
4. First Aid Measures
Ingestion
Drink copious amounts of water an provide fresh air. Immediately call a doctor.
Inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult a doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transport.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
No further relevant information available.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
HAZCHEM
Unsuitable extinguishing agents: Water
Special protective equipment and precautions for fire fighters
Mouth respiratory protective device
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Dilute with plenty of water. Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binde3rs, universal binders, sawdust). Use neutralizing agent. Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agent.
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges. Keep respiratory protective device available.
Conditions for safe storage
Store in a cool location. Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
Ethyl Alcohol
1000ppm
1900 mg/m³
Methyl Alcohol
200 ppm
260 mg/m³
-
Hydrogen Chloride
5 ppm
7 mg/m³
-
Methyl Alcohol
-
-
-
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles
Skin protection
Protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Body protection
Not available
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
9. Physical and Chemical Properties
General information
Appearance
Liquid. Colour according to product specification
Odour
Alcohol-like
pH
1.1-1.4 · pH-value at 20 °C (68 °F)
Vapour Pressure
59 hPa (44.3 mm Hg) at 20 °C (68 °F)
Density
Not determined
Boiling Point
78 °C (172.4 °F)
Melting Point
Undetermined
Solubility
Fully miscible
Specific Gravity of Density
No further relevant information available
Flash Point
13 °C (55.4 °F)
Flammable (Explosive) Limits
Lower: 3.5 Vol %
Upper: 15 Vol %
Ignition Temperature
425 °C (797 °F)
Formula
Not available
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications
Possibility of hazardous reactions
Contact with water releases flammable gases
Conditions to avoid
No further relevant information available
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
67-56-1 Methyl Alcohol
Oral LD50 5,628 mg/kg (rat)
Dermal LD50 15,800 mg/kg (rabbit)
Eye contact
Strong caustic effect. Strong irritant with the danger of severe eye injury.
Skin contact
Strong caustic effect on skin and mucous membranes.
Ingestion
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
Inhalation
Not available
Toxicity and irritation
Harmful, corrosive, irritant, carcinogenic
12. Ecological Information
Ecotoxicity
No further relevant information available
Persistence and degradability
No further relevant information available
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pHvalue harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that
after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous.
13. Disposal Considerations
General information
Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations. Cleanse with water, if necessary with cleansing agent.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.