Aldehyde-fuchsin Solution, pH1.0

1. Identification

Product Identifiers

Product Name

Aldehyde-fuchsin Solution, pH1.0

Other Names

Not available

Product Number(s)

26120-03, 26328-01, EMS26120-03, EMS26328-01

CAS Number

Not available

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

• Hazard-determining components of labelling:
• Ethyl alcohol
• hydrogen chloride
• 4,4'-(4-iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride
• Highly flammable liquid and vapour.
• In contact with water releases flammable gases which may ignite spontaneously.
• Causes severe skin burns and eye damage.
• May cause cancer.

Precautionary Statement(s)

• Obtain special instructions before use.
• Do not handle until all safety precautions have been read and understood.
• Keep away from heat/sparks/open flames/hot surfaces. No smoking.
• Keep away from any possible contact with water, because of violent reaction and possible flash fire.
• Handle and store contents under inert gas. Protect from moisture.
• Keep container tightly closed.
• Ground/bond container and receiving equipment.
• Use explosion-proof electrical/ventilating/lighting equipment.
• Use only non-sparking tools.
• Take precautionary measures against static discharge.
• Do not breathe dusts or mists.
• Wash thoroughly after handling.
• Wear protective gloves/protective clothing/eye protection/face protection.

Primary route(s) of entry

Human Health

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Ingestion

Rinse mouth. Do not induce vomiting.

Eyes

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CNETER/Doctor.

Skin

(or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse.

Environment

3. Composition / Information on Ingredients

4. First Aid Measures

Ingestion

Drink plenty of water and provide fresh air. Call for a doctor immediately.

Inhalation

• Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
• In case of unconsciousness place patient stably in side position for transportation.

Skin Contact

Immediately wash with water and soap and rinse thoroughly.

Eye Contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Other Information

• Immediately remove any clothing soiled by the product.
• Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

CO₂, sand, extinguishing powder. Do not use water.

HAZCHEM

For safety reasons unsuitable extinguishing agents: Wate with full jet.

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental precautions

Do not allow to enter sewers/surface or ground water.

Methods and materials for containment and clean up

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
• Use neutralising agent.
• Dispose contaminated material as waste according to item 13.
• Ensure adequate ventilation.
• Do not flush with water or aqueous cleansing agents.
• Protective Action Criteria for Chemicals
• PAC-1:
• 64-17-5 Ethyl alcohol 1,800 ppm
• 67-56-1 Methyl Alcohol 530 ppm
• 7647-01-0 hydrogen chloride 1.8 ppm
• 123-63-7 2,4,6-trimethyl-1,3,5-trioxan 14 mg/m³
• PAC-2:
• 64-17-5 Ethyl alcohol 3,300* ppm
• 67-56-1 Methyl Alcohol 2,100 ppm
• 7647-01-0 hydrogen chloride 22 ppm
• 123-63-7 2,4,6-trimethyl-1,3,5-trioxan 150 mg/m³
• PAC-3:
• 64-17-5 Ethyl alcohol 15000* ppm
• 67-56-1 Methyl Alcohol 7200* ppm
• 7647-01-0 hydrogen chloride 100 ppm
• 123-63-7 2,4,6-trimethyl-1,3,5-trioxan 930 mg/m³

7. Handling and Storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.
• Open and handle receptacle with care.
• Prevent formation of aerosols.
• Keep ignition sources away - Do not smoke.
• Protect from heat.
• Protect against electrostatic charges.
• Keep respiratory protective device available.

Conditions for safe storage

• Store in a cool location.
• Keep container tightly sealed.
• Store in cool, dry conditions in well sealed receptacles.
• Protect from heat and direct sunlight.

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

• Keep away from foodstuffs, beverages and feed.
• Immediately remove all soiled and contaminated clothing.
• Wash hands before breaks and at the end of work.
• Store protective clothing separately.
• Avoid contact with the eyes.
• Avoid contact with the eyes and skin.

Personal protective equipment

Eye and face protection

Tightly sealed goggles.

Skin protection

Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Body protection

Wear protective clothing.

Respiratory protection

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

9. Physical and Chemical Properties

General information

Appearance

Violet liquid

Odour

Alcohol-like

pH

1.95-1.05

Vapour Pressure

59hPa

Density

Not determined

Boiling Point

78°C

Melting Point

Undetermined

Solubility

Not miscible or difficult to mix.

Specific Gravity of Density

Not available

Flash Point

13°C

Flammable (Explosive) Limits

• Lower: 3.5 Vol%
• Upper: 15 Vol%

Ignition Temperature

425°C

Formula

Not available

10. Stability and Reactivity

Reactivity

No further relevant information available.

Chemical stability

No decomposition if used according to specifications.

Possibility of hazardous reactions

Contact with water releases flammable gases.

Conditions to avoid

No further relevant information available.

Incompatible materials

No further relevant information available.

11. Toxicological Information

Acute effects

• 67-56-1 Methyl Alcohol
• Oral LD50 5628 mg/kg (rat)
• Dermal LD50 15800 mg/kg (rabbit)

Eye contact

• Strong caustic effect.
• Strong irritant with the danger of severe eye injury.

Skin contact

Strong caustic effect on skin and mucous membranes.

Ingestion

Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach.

Inhalation

No sensitising effects known.

Toxicity and irritation

• Harmful
• Corrosive
• Irritant
• Carcinogenic
• Carcinogenic categories
• IARC (International Agency for Research on Cancer)
• 64-17-5 Ethyl alcohol 1
• 7647-01-0 hydrogen chloride 3
• 569-61-9 4,4'-(4-iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride 2B
• NTP (National Toxicology Program)
• 569-61-9 4,4'-(4-iminocyclohexa-2,5-dienylidenemethylene)dianiline hydrochloride R
• OSHA-Ca (Occupational Safety Health Administration)
• None of the ingredients is listed.

12. Ecological Information

Ecotoxicity

No further relevant information available.

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Other adverse effects

• Water hazard class 3: extremely hazardous for water.
• Do not allow product to reach ground water, water course or sewage system, even in small quantities.
• Must not reach sewage water or drainage ditch undiluted or unneutralised.
• Danger to drinking water if even extremely small quantities leak into the ground.
• Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

For safety reasons unsuitable extinguishing agents: Wate with full jet.

UN Number

UN2924

Proper shipping name

2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. (ETHANOL (ETHYL ALCOHOL), METHANOL)

Transport hazard class

• Class 3 Flammable liquids
• Label 3±8

Packing group

II

Environmental hazard

Not applicable.

Special precautions for users

• Warning: Flammable liquids.
• Hazard identification number (Kemler code): 338
• EMS Number: F-E,S-C
• Stowage Category: B
• Stowage Code: SW2 Clear of living quarters.

Additional information

• Limited quantities (LQ) 1L
• Excepted quantities (EQ) Code: E2
• Maximum net quantity per inner packaging: 30mL
• Maximum net quantity per outer packaging: 500mL
• Transport category: 2
• Tunnel restriction code: D/E

15. Regulatory Information

Poisons Schedule Number

• 67-56-1 Methyl Alcohol S5, S6, S10
• 7647-01-0 hydrogen chloride S5, S6
• 123-63-7 2,4,6-trimethyl-1,3,5-trioxan S4

Other Information

• Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases.
• A Chemical Safety Assessment has not been carried out.

16. Other Information

SDS preparation date

15 July 2026

Comments

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

References

EMS SDS "Aldehyde-Fuchsin Solution, pH 1.0" 11/08/2022 https://www.emsdiasum.com/docs/technical/msds/26328-01.pdf