AMMONIUM HYDROXIDE, CONCENTRATE

1. Identification

Product Identifiers

Product Name

Ammonium Hydroxide, Concentrated

Other Names

Ammonia solution, Ammonia water, Aqua ammonia, Aqueous ammonia, or Ammoniacal liquor

Product Number(s)

EMS26392-02

CAS Number

1336-21-6

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

• Components of labelling that determine hazards: ammonia
• Hazard statements: Causes severe skin burns and eye damage.

Precautionary Statement(s)

• Do not breathe dusts or mists.
• Wash thoroughly after handling.
• Wear eye protection/face protection.
• Wear protective gloves/protective clothing/eye protection/face protection.
• If swallowed: Rinse mouth. Do NOT induce vomiting.
• If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
• If inhaled: Remove person to fresh air and keep comfortable for breathing.
• If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
• Continue rinsing.
• Immediately call a poison center/doctor.
• Specific treatment (see on this label).
• Wash contaminated clothing before reuse.
• Store locked up.
• Dispose of contents/container in accordance with local/regional/national/international regulations.

Primary route(s) of entry

Human Health

Inhalation

If inhaled: Remove person to fresh air and keep comfortable for breathing.

Ingestion

If swallowed: Rinse mouth. Do NOT induce vomiting

Eyes

• Wear eye protection/face protection.
• If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
• Continue rinsing.
• Immediately call a poison center/doctor.

Skin

• Wear protective gloves/protective clothing/eye protection/face protection.
• If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
• Wash contaminated clothing before reuse.

Environment

3. Composition / Information on Ingredients

4. First Aid Measures

Ingestion

Drink copious amounts of water and provide fresh air. Immediately call a doctor

Inhalation

In case of unconsciousness, place the patient stably in the side position for transportation.

Skin Contact

Immediately wash with water and soap and rinse thoroughly.

Eye Contact

Rinse the opened eye for several minutes under running water. Then consult a doctor.

Other Information

Immediately remove any clothing soiled by the product.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

Use firefighting measures that suit the environment.

HAZCHEM

No further relevant information is available.

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental precautions

• Inform respective authorities in case of seepage into a watercourse or sewage system.
• Dilute with plenty of water.
• Do not allow to enter sewers/surface or ground water.

Methods and materials for containment and clean up

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, or sawdust).
• Use a neutralizing agent.
• Dispose of contaminated material as waste according to section 13.
• Ensure adequate ventilation.

7. Handling and Storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.
• Prevent formation of aerosols

Conditions for safe storage

• Requirements to be met by storerooms and receptacles: No special requirements.
• Information about storage in one common storage facility: Not required.
• Further information about storage conditions: Keep the receptacle tightly sealed.
• Specific end use(s) No further relevant information is available.

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

No further data; see section 7

Personal protective equipment

Eye and face protection

• Avoid contact with the eyes and skin.
• Tightly sealed goggles

Skin protection

• Keep away from foodstuffs, beverages, and feed.
• Immediately remove all soiled and contaminated clothing.
• Wash hands before breaks and at the end of work.

Body protection

• Protective gloves
• The glove material has to be impermeable and resistant to the product, the substance, or the preparation.
• Due to missing tests no recommendation to the glove material can be given for the product/the preparation/the
• chemical mixture.
• Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
• Material of gloves
• The selection of the suitable gloves does not only depend on the material but also on further marks of quality and
• varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
• The glove material can not be calculated in advance and therefore has to be checked prior to the application.
• Penetration time of glove material
• The exact breakthrough through time has to be found out by the manufacturer of the protective gloves and has to be
• observed

Respiratory protection

• Breathing equipment:
• In case of brief exposure or low pollution, use a respiratory filter device. In case of intensive or longer exposure, use
• respiratory protective device that is independent of circulating air.

9. Physical and Chemical Properties

General information

Appearance

Colourless Liquid

Odour

Ammonia-like

pH

at 20 °C (68 °F): 13.8

Vapour Pressure

23 hPa (17.3 mm Hg)

Density

-

Boiling Point

100 °C (212 °F)

Melting Point

-72 °C (-97.6 °F)

Solubility

Fully miscible

Specific Gravity of Density

at 20 °C (68 °F): 0.9692 g/cm³ (8.08797 lbs/gal)

Flash Point

Not applicable.

Flammable (Explosive) Limits

Not flammable

Ignition Temperature

Product is not selfigniting

Formula

NH4OH

10. Stability and Reactivity

Reactivity

No further relevant information is available.

Chemical stability

Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications.

Possibility of hazardous reactions

No dangerous reactions are known.

Conditions to avoid

No further relevant information is available.

Incompatible materials

• No further relevant information is available.
• No dangerous decomposition products are known.

11. Toxicological Information

Acute effects

No sensitizing effects known.

Eye contact

• Strong caustic effect.
• Strong irritant with the danger of severe eye injury

Skin contact

Strong caustic effect on skin and mucous membranes

Ingestion

Swallowing will lead to a strong caustic effect on the mouth and throat and to the danger of perforation of the esophagus and stomach.

Toxicity and irritation

• The product shows the following dangers according to internally approved calculation methods for preparations:
• Corrosive
• Irritant

12. Ecological Information

Ecotoxicity

· Aquatic toxicity: No further relevant information is available

Persistence and degradability

No further relevant information is available

Bioaccumulative potential

No further relevant information is available

Other adverse effects

• General notes:
• Water hazard class 2 (Self-assessment): hazardous for water
• Do not allow the product to reach groundwater, a watercourse, or a sewage system.
• Must not reach bodies of water or drainage ditches undiluted or unneutralized.
• Danger to drinking water if even small quantities leak into the ground.
• Also poisonous for fish and plankton in water bodies.
• Very toxic for aquatic organisms
• Rinsing off bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH value harms aquatic organisms. In the dilution of the use-level, the pH value is considerably reduced so that after the use of the product, the aqueous waste, emptied into drains, is only low-water dangerous.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

No further relevant information is available.

UN Number

UN2672

Proper shipping name

• DOT Ammonia solution
• ADR 2 6 7 2 AMMONIA SOLUTION, ENVIRONMENTALLY HAZARDOUS
• IMDG AMMONIA SOLUTION, MARINE POLLUTANT
• IATA AMMONIA SOLUTION

Transport hazard class

• Class 8 Corrosive substances
• Label 8

Packing group

III

Environmental hazard

• Marine pollutant: Yes (DOT)
• Symbol (fish and tree)
• Special marking (ADR): Symbol (fish and tree)

Special precautions for users

• Warning: Corrosive substances
• Hazard identification number (Kemler code): 90
• EMS Number: F-A,S-F
• Segregation groups (SGG2) Ammonium compounds, (SGG18) alkalis
• Stowage Category A

Additional information

• UN 2672 AMMONIA SOLUTION, 8, III, ENVIRONMENTALLY HAZARDOUS
• Limited quantities (LQ) 5L
• Excepted quantities (EQ) Code: E1
• Maximum net quantity per inner packaging: 30 mL
• Maximum net quantity per outer packaging: 1000 mL

15. Regulatory Information

Poisons Schedule Number

No further relevant information is available.

Other Information

• GHS05
• Signal word Danger
• Hazard-determining components of labeling: ammonia
• Hazard statements
• Causes severe skin burns and eye damage.
• Precautionary statements
• Do not breathe dusts or mists.
• Wash thoroughly after handling.
• Wear eye protection/face protection.
• Wear protective gloves/protective clothing/eye protection/face protection.
• If swallowed: Rinse mouth. Do NOT induce vomiting.
• If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
• If inhaled: Remove person to fresh air and keep comfortable for breathing.
• If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
• Continue rinsing.
• Immediately call a poison center/doctor.
• Specific treatment (see on this label).
• Wash contaminated clothing before reuse.
• Store locked up.
• Dispose of contents/container in accordance with local/regional/national/international regulations.
• Chemical safety assessment: A chemical safety assessment has not been carried out.

16. Other Information

SDS preparation date

15 February 2026

Comments

• ** This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
• Abbreviations and acronyms:
• ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
• Carriage of Dangerous Goods by Road)
• IMDG: International Maritime Code for Dangerous Goods
• DOT: US Department of Transportation
• IATA: International Air Transport Association
• EINECS: European Inventory of Existing Commercial Chemical Substances
• ELINCS: European List of Notified Chemical Substances
• CAS: Chemical Abstracts Service (division of the American Chemical Society)
• NFPA: National Fire Protection Association (USA)
• HMIS: Hazardous Materials Identification System (USA)
• VOC: Volatile Organic Compounds (USA, EU)
• PBT: Persistent, Bioaccumulative and Toxic
• vPvB: very Persistent and very Bioaccumulative
• NIOSH: National Institute for Occupational Safety
• OSHA: Occupational Safety Health
• TLV: Threshold Limit Value
• PEL: Permissible Exposure Limit
• REL: Recommended Exposure Limit

References

EMS SDS Ammonium hydroxide, concentrated. https://www.emsdiasum.com/docs/technical/msds/26392-02.pdf 28/04/2025