Call a poison center/doctor if you feel unwell. Rinse mouth.
Eyes
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin
Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention.
Environment
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
glycerol
56-81-5
>50-≤100%
Mixtures
triethylenediamine
280-57-9
>2.5-≤10%
Mixtures
4. First Aid Measures
Ingestion
Immediately call a doctor.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
Use fire fighting measures that suit the environment.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
No special measures required.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Conditions for safe storage
Keep receptacle tightly sealed.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
glycerol
-
-
-
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Not available.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
9. Physical and Chemical Properties
General information
Appearance
Colourless liquid.
Odour
Mild
pH
Not determined.
Vapour Pressure
0.1hPa
Density
Not determined.
Boiling Point
>100 °C (>212 °F)
Melting Point
Undetermined.
Solubility
Fully miscible.
Specific Gravity of Density
Not determined.
Flash Point
160°C (320 °F)
Flammable (Explosive) Limits
Not determined.
Ignition Temperature
Product is not selfigniting.
Formula
Not available.
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
280-57-9 triethylenediamine
Oral LD50 1700mg/kg (rat).
Eye contact
Irritating effect.
Skin contact
Irritant to skin and mucous membranes. Sensitization possible through skin contact.
Ingestion
Not available.
Inhalation
Not available.
Toxicity and irritation
Harmful
Irritant
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 1: slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13. Disposal Considerations
General information
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
recommended cleansing agent: Water, if necessary with cleansing agents.
14. Transport Information
ADG label required
HAZCHEM
No further relevant information available.
UN Number
Not available
Proper shipping name
Not available.
Transport hazard class
Not available.
Packing group
Not available.
Environmental hazard
Not applicable.
Special precautions for users
Not applicable.
Additional information
Not available.
15. Regulatory Information
Poisons Schedule Number
None of the ingredients is listed.
Other Information
A Chemical Safety Assessment has not been carried out.
16. Other Information
SDS preparation date
27 November 2024
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.