Inhalation (vapours); also skin contact, eye contact, and accidental ingestion.
Human Health
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion
Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. Rinse mouth.
Eyes
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention.
Skin
(or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention.
Environment
In case of fire: Use CO₂, powder or water spray for extinction.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
toluene
108-88-3
45-70%
-
Acrylic Resin
28262-63-7
10-30%
-
BBP
85-68-7
1-5%
-
Butylated hydroxytoluene
128-37-0
0.1-1%
-
4. First Aid Measures
Ingestion
Call for a doctor immediately.
Inhalation
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
CO₂, sand, extinguishing powder. Do not use water.
HAZCHEM
Not available.
Special protective equipment and precautions for fire fighters
For safety reasons unsuitable extinguishing agents: Water with full jet.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents.
Protective Action Criteria for Chemicals
PAC-1:
108-88-3 toluene 67 ppm
85-68-7 BBP 15 mg/m³
PAC-2:
108-88-3 toluene 560 ppm
85-68-7 BBP 77 mg/m³
PAC-3:
108-88-3 toluene 3700* ppm
85-68-7 BBP 460 mg/m³
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Conditions for safe storage
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Keep respiratory protective device available.
Store in a cool location.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
Keep container in a well-ventilated place.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
toluene
100 ppm
375 mg/m³
150 ppm
560 mg/m³,-
Butylated hydroxytoluene
NA
10 mg/m³
NA
NA
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material.
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Wear protective clothing.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. Physical and Chemical Properties
General information
Appearance
Colourless liquid
Odour
Aromatic
pH
Not determined.
Vapour Pressure
at 20 °C: 62.7hPa
Density
0.97g/cm³
Boiling Point
110.6 °C
Melting Point
Undetermined.
Solubility
Not miscible or difficult to mix with water.
Specific Gravity of Density
Not determined.
Flash Point
4.4 °C (39.9 °F)
Flammable (Explosive) Limits
Lower: 1.2 Vol %
Upper: 7.0 Vol %
Ignition Temperature
535 °C (995 °F)
Formula
Not available.
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
LD/LC50 values relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
Eye contact
Irritating effect.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
No further relevant information available.
Inhalation
No sensitising effects known.
Toxicity and irritation
The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version.
Harmful.
Irritant.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
108-88-3 toluene 3
6002385-68-7 BBP 3
128-37-0 Butylated hydroxytoluene 3
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety Health Administration)
None of the ingredients is listed.
12. Ecological Information
Ecotoxicity
Toxic for fish.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms.
13. Disposal Considerations
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.