Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
Eye Contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Show this material safety data sheet to the doctor in attendance.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
CO₂, sand, extinguishing powder. Do not use water / Water with full jet.
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
HAZCHEM
Not available.
Special protective equipment and precautions for fire fighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
Environmental precautions
Do not allow to enter sewers/ surface or ground water. Risk of explosion.
Methods and materials for containment and clean up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.
7. Handling and Storage
Precautions for safe handling
Advice on safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols. Do not inhale substance/mixture.
Advice on protection against fire and explosion.
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
Conditions for safe storage
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorised persons.
Storage class
Storage class (TRGS 510): 3: Flammable liquids
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
1330-20-7 xylene
50 ppm
220 mg/m³
100 ppm
441 mg/m³
108-88-3 Toluene
50 ppm
191 mg/m³
150 ppm
574 mg/m³
84-74-2 dibutyl phthalate
5 mg/m³
Engineering controls
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Personal protective equipment
Eye and face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Avoid contact with the skin.
Wear tightly sealed goggles.
Skin protection
Avoid contact with the eyes and skin. Wear protective gloves. Required.
Body protection
Flame retardant antistatic protective clothing.
Immediately remove all soiled and contaminated clothing.
Respiratory protection
required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
9. Physical and Chemical Properties
General information
Appearance
Clear colourless liquid
Odour
Characteristic
pH
Not available.
Vapour Pressure
6.7 hPa at 20°C
Density
Not available.
Boiling Point
144 °C
Melting Point
Undetermined.
Solubility
Not miscible or difficult to mix with water.
Specific Gravity of Density
Not available.
Flash Point
27 °C
Flammable (Explosive) Limits
Product is not self igniting. Product is not explosive. However, formation of explosive air/vapour mixtures are possible. Explosion limits: Lower: 1.1 Vol % Upper: 7 Vol %
Ignition Temperature
390 °C (734 °F)
Formula
Not available.
10. Stability and Reactivity
Reactivity
Vapors may form explosive mixture with air.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature).
Symptoms: Possible symptoms:, mucosal irritations, Cough, Shortness of breath, Possible
damages:, damage of respiratory tract
Dermal: No data available
Eye contact
Remarks: Mixture causes serious eye irritation.
Skin contact
Causes skin irritation.
Ingestion
No further relevant information available.
Inhalation
No further relevant information available.
Toxicity and irritation
Reproductive toxicitySuspected of damaging fertility. Suspected of damaging the unborn child.
Mixture may cause respiratory irritation.
Mixture may cause drowsiness or dizziness.
Mixture may cause damage to organs through prolonged or repeated exposure.
Central nervous system, Liver, Kidney.
Additional Information:
Exposure can cause damage to the:, Central nervous system depression, Dermatitis, Anorexia., Bronchitis., Tremors, Blurred vision, Incoordination., Headache, Vomiting, Dizziness, Weakness, anemia, Prolonged or repeated exposure to skin causes defatting and dermatitis.
Other dangerous properties can not be excluded.
This substance should be handled with particular care.
Handle in accordance with good industrial hygiene and safety practice.
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.
13. Disposal Considerations
General information
Waste material must be disposed of in accordance with the national and local regulations.
Leave chemicals in original containers. No mixing with other waste. Handle uncleaned