H304: May be fatal if swallowed and enters airways
H315: Causes serious skin irritation
H336: May cause drowsiness or dizzeness
H361: Suspected of damaging fertility or the unborn child
H373: May cause damage to organs through prolonged or repeated exposure
H412: Harmful to aquatic life with long term effects
Precautionary Statement(s)
P210: Keep away from flames and hot surfaces. No smoking
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P273: Avoid release to the environment
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301±P310: If swallowed: Immediately call a poison center/doctor
P303±P361±P353: If on skin (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower
P303±P351±P338: IF IN EYES Rinse cautiously with water for several minutes, Remove contact lenses, Continue rinsing
P312: Call a POISON center/doctor if you feel unwell
P405 Store locked up.
P501: Dispose of contents/container in accordance with local regional/national/international regulations.
Primary route(s) of entry
Inhalation, absorption through skin contact, ingestion
Human Health
Inhalation
Harmful if inhaled
Ingestion
May be fatal if swallowed
Eyes
Not available.
Skin
Causes serious skin irritation
Environment
Do not allow to enter sewers/ surface or ground water.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
Tolulene
108-88-3
>= 70 - < 90%
Flam. Liq. 2; 2; Repr. 2; STOT SE 3; STOT RE 2; Asp. Tox. 1; H225, H315, H361, H336, H373, H304Concentration limits: 20 %: STOT SE 3, H336;
4. First Aid Measures
Ingestion
After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary failure possible after aspiration of vomit. Call a physician immediately. Subsequently administer: activated charcoal (20 - 40 g in 10% slurry). More severe effects if alcohol is consumed
Inhalation
After inhalation: fresh air. If breathing stops: mouth-to-mouth breathing or artificial respiration. Oxygen if necessary. Immediately call in physician.
Skin Contact
After skin contact: wash off with plenty of water. Remove contaminated clothing. Consult a physician.
Eye Contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
Other Information
Most important symptoms and effects, both acute and delayed irritant effects,
Drying-out effect resulting in rough and chapped skin.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
Foam, Carbon dioxide (CO₂)
** For this substance/mixture no limitations of extinguishing agents are given.
HAZARDS ARISING FROM MIXTURE:
Carbon oxides
Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.
Remove container from danger zone and cool with water
Prevent fire extinguishing water from contaminating surface water or the ground water system
Do not let product enter drains.
Risk of explosion.
Large Fire
Foam, Carbon dioxide (CO₂), Dry powder
HAZCHEM
*3Y
Special protective equipment and precautions for fire fighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel:
Do not breathe vapours, aerosols.
Avoid substance contact.
Ensure adequate ventilation.
Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders: Protective equipment see section 8.
Environmental precautions
Do not let product enter drains. Risk of explosion.
Methods and materials for containment and clean up
Cover drains
Collect, bind, and pump off spills.
Observe possible material restrictions (see sections 7 and 10)
Take up with liquid-absorbent material (e.g. Chemizorb® ).
Dispose of properly
Clean up affected area.
7. Handling and Storage
Precautions for safe handling
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Conditions for safe storage
Keep container tightly closed in a dry and well-ventilated place
Keep away from heat and sources of ignition.
Store at ±15°C to ±25°C.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
Tolulene (108-88-3)
50 ppm
188 mg/m³
-
-
Engineering controls
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Personal protective equipment
Eye and face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Full contact
Material: Viton®
Minimum layer thickness: 0.7 mm
Break through time: > 480 min
Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
Body protection
Flame retardant antistatic protective clothing. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Respiratory protection
Required when vapours/aerosols are generated.
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented
9. Physical and Chemical Properties
General information
Appearance
Liquid colourless
Odour
Characteristic
pH
Not available.
Vapour Pressure
No data available
Density
No data available
Boiling Point
No data available
Melting Point
No data available
Solubility
at 20 °C practically insoluble
Specific Gravity of Density
No data available
Flash Point
8 °C
Flammable (Explosive) Limits
Not classified as explosive.
Ignition Temperature
No data available
Formula
Viscosity, kinematic: No data available
Viscosity, dynamic: 60 - 100 mPa.s at 20 °C
10. Stability and Reactivity
Reactivity
Vapors may form explosive mixture with air.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Toxicity to bacteria static test EC50 - Bacteria - 84 mg/l - 24 h
Remarks: (ECHA)
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Discharge into the environment must be avoided.
13. Disposal Considerations
General information
Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
14. Transport Information
ADG label required
Class 3 Flammable liquid
HAZCHEM
*3Y
UN Number
UN1866
Proper shipping name
Resin solution
Transport hazard class
3
Packing group
PG II
Environmental hazard
No information available
Special precautions for users
Warning: Flammable liquids
Hazard identification number (Kemler code): 30
EMS Number: F-E,S-E
Stowage Category A
Additional information
Quantity limitations On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
15. Regulatory Information
Poisons Schedule Number
-
Other Information
-
16. Other Information
SDS preparation date
28 November 2024
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.