Immediately call a poison center/doctor. Do NOT induce vomiting
Eyes
Not available
Skin
If on skin: Wash with plenty of water.
IF exposed or concerned: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Environment
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
®-p-mentha-1,8-diene
5989-27-5
60-80%
Mixture
Methyl Methacrylate
80-62-6
0.1-1%
Mixture
N-BUTYL METHACRYLATE, MONOMER
0.1-1%
Mixture
4. First Aid Measures
Ingestion
If symptoms persist consult doctor.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water.
Other Information
No further relevant information available.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
Use fire fighting measures that suit the environment.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
No special measures required
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
Protective Action Criteria for Chemicals
PAC-1:
5989-27-5 ®-p-mentha-1,8-diene 15 ppm
80-62-6 Methyl Methacrylate 17 ppm
N-BUTYL METHACRYLATE, MONOMER 19 mg/m³
PAC-2:
5989-27-5 ®-p-mentha-1,8-diene 67 ppm
80-62-6 Methyl Methacrylate 120 ppm
N-BUTYL METHACRYLATE, MONOMER 210 mg/m³
PAC-3:
5989-27-5 ®-p-mentha-1,8-diene 170 ppm
80-62-6 Methyl Methacrylate 570 ppm
N-BUTYL METHACRYLATE, MONOMER 1,300 mg/m³
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace
Prevent formation of aerosols.
Conditions for safe storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
Specific end use(s) No further relevant information available.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
Methyl Methacrylate
50ppm
100 mg/m³
100ppm
410mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Goggles recommended during refilling.
Skin protection
rotective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Not available
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
9. Physical and Chemical Properties
General information
Appearance
Liquid coloured according to product specification.
Odour
Characteristic
pH
Mixture is non-polar/aprotic.
Vapour Pressure
2.3hPa at 20°C
Density
0.85078 g/cm³ (7.09976 lbs/gal)
Boiling Point
173 °C (343.4 °F) at 20 °C (68 °F)
Melting Point
Undetermined
Solubility
Fully miscible
Specific Gravity of Density
Not available
Flash Point
Not applicable
Flammable (Explosive) Limits
Lower: 0.7 Vol%
Upper: 6.1 Vol%
Ignition Temperature
255°C
Formula
Not available
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
LD/LC50 values that are relevant for classification:
5989-27-5 ®-p-mentha-1,8-diene
Oral LD50 4,400 mg/kg (rat)
Eye contact
No irritating effect.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
Not available.
Inhalation
Not available
Toxicity and irritation
Sensitization possible through skin contact
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Very toxic for fish.
Harmful to fish
Water hazard class 2: hazardous for water.
Do not allow product to reach ground water course, or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms.
13. Disposal Considerations
General information
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.