Glutaraldehyde/Paraformaldehyde, 0.1M Phosphate Buffered - 1%/4%

1. Identification

Product Identifiers

Product Name

Glutaraldehyde/Paraformaldehyde, 0.1M Phosphate Buffered - 1%/4%

Other Names

Not available

Product Number(s)

15949-70, 15949-70-SP, 15949-80, CEMS15949-70, CEMS15949-80

CAS Number

Not available.

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

• Hazard-determining components of labelling:
• formaldehyde
• Glutaraldehyde
• Causes skin irritation.
• Causes serious eye irritation.
• May cause allergy or asthma symptoms or breathing difficulties if inhaled.
• May cause an allergic skin reaction.
• Suspected of causing genetic defects.
• May cause cancer.
• May cause respiratory irritation.

Precautionary Statement(s)

• Obtain special instructions before use.
• Do not handle until all safety precautions have been read and understood.
• Avoid breathing dust/fume/gas/mist/vapours/spray.
• Wash thoroughly after handling.
• Use only outdoors or in a well-ventilated area.
• Contaminated work clothing should not be allowed out of the workplace.
• Wear protective gloves/protective clothing/eye protection/face protection.
• Wear respiratory protection.

Primary route(s) of entry

Human Health

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor.

Ingestion

Get medical advice/attention.

Eyes

• Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• If eye irritation persists: Get medical advice/attention.

Skin

• Wash with plenty of water. Take off contaminated clothing and wash it before reuse.
• If skin irritation or rash occurs: Get medical advice/attention.

Environment

3. Composition / Information on Ingredients

4. First Aid Measures

Ingestion

Call for a doctor immediately.

Inhalation

• Supply fresh air and to be sure call for a doctor.
• In case of unconsciousness place patient stably in side position for transportation.

Skin Contact

Immediately wash with water and soap and rinse thoroughly.

Eye Contact

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Other Information

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

Use fire extinguishing methods suitable to surrounding conditions.

HAZCHEM

No further relevant information available.

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Not required.

Environmental precautions

• Inform respective authorities in case of seepage into water course or sewage system.
• Do not allow to enter sewers/surface or ground water.

Methods and materials for containment and clean up

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
• Dispose contaminated material as waste according to item 13.
• Ensure adequate ventilation.

7. Handling and Storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.
• Open and handle receptacle with care.
• Prevent formation of aerosols.
• Keep respiratory protective device available.

Conditions for safe storage

Keep container tightly sealed.

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

• Keep away from foodstuffs, beverages and feed.
• Immediately remove all soiled and contaminated clothing.
• Wash hands before breaks and at the end of work.
• Store protective clothing separately.
• Avoid Contact with the eyes and skin.

Personal protective equipment

Eye and face protection

Tightly sealed goggles.

Skin protection

• Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation.
• The selection of glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Body protection

Protective clothing.

Respiratory protection

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

9. Physical and Chemical Properties

General information

Appearance

Clear liquid

Odour

Fruit-like

pH

Not determined.

Vapour Pressure

23hPa

Density

Not determined.

Boiling Point

100°C

Melting Point

Undetermined.

Solubility

Not miscible or difficult to mix.

Specific Gravity of Density

Not available.

Flash Point

Not applicable.

Flammable (Explosive) Limits

Not determined.

Ignition Temperature

Product is not selfigniting.

Formula

• Organic solvents: 4.0%
• Water: 95.0%
• VOC (EC): 4.0%

10. Stability and Reactivity

Reactivity

No further relevant information available.

Chemical stability

No decomposition if used according to specifications.

Possibility of hazardous reactions

No dangerous reactions known.

Conditions to avoid

No further relevant information available.

Incompatible materials

No further relevant information available.

11. Toxicological Information

Acute effects

• 50-00-0 formaldehyde
• Oral LD50 >200mg/kg (rat)

Eye contact

Irritating effect.

Skin contact

Irritant to skin and mucous membranes. Sensitisation possible through skin contact.

Ingestion

Not available.

Inhalation

Sensitisation possible through inhalation.

Toxicity and irritation

• Harmful
• Irritant
• Carcinogenic

12. Ecological Information

Ecotoxicity

No further relevant information available.

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Other adverse effects

• Harmful to fish.
• Water hazard class 2: Hazardous for water.
• Do not allow product to reach ground water, water course or sewage system.
• Danger to drinking water if even small quantities leak into the ground.
• Harmful to aquatic organisms.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

No further relevant information available.

UN Number

UN1760

Proper shipping name

1760 CORROSIVE LIQUID, N.O.S (Glutaraldehyde, FORMALDEHYDE SOLUTION)

Transport hazard class

8 Corrosive substances.

Packing group

II

Environmental hazard

Not applicable.

Special precautions for users

• Warning: Corrosive substances.
• Hazard identification number (Kemler code): 80
• EMS Number: F-A,S-B
• Segregation groups: Acids
• Stowage Category: B
• Stowage Code: SW2 Clear of living quarters.

Additional information

• Limited quantities (LQ): 1L
• Excepted quantities (EQ) Code: E2
• Maximum net quantity per inner packaging: 30mL
• Maximum net quantity per outer packaging: 500mL

15. Regulatory Information

Poisons Schedule Number

• 50-00-0 formaldehyde S2, S6, S10
• 111-30-8 Glutaraldehyde S2, S5, S6

Other Information

• Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
• Exceptions can be made by the authorities in certain cases.
• A Chemical Safety Assessment has not been carried out.

16. Other Information

SDS preparation date

23 February 2026

Comments

The information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shallnot esablish a legally valid contractual relationship.