Wear personal protective equipment/face protection.
Primary route(s) of entry
Not available.
Human Health
Inhalation
If exposed or concerned: Get medical advice/attention.
Ingestion
If exposed or concerned: Get medical advice/attention.
Eyes
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin
Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Environment
Explosion risk in case of fire. DO NOT fight fire when fire reaches explosives. Evacuate area. Store in accordance with local/regional/national/international regulations. Store locked up. Protect from sunlight. Store at temperatures not exceeding 32°C. Keep cool. Store away from other materials. Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
dibenzoyl peroxide
94-36-0
>50-≤100%
Not Available
dicyclohexyl phthalate
84-61-7
>25-≤50%
Not Available
4. First Aid Measures
Ingestion
If symptoms persist consult doctor.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
No further relevant information available.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
Use fire extinguishing methods suitable to surrounding conditions.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
No special measures required.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Remove persons from danger area.
Environmental precautions
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Pick up mechanically.
7. Handling and Storage
Precautions for safe handling
Open and handle receptacle with care.
Keep ignition sources away - Do not smoke.
Prevent impact and friction.
Conditions for safe storage
Keep container tightly sealed.
Protect from heat and direct sunlight.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
dibenzoyl peroxide
5mg/m³
-
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Protective clothing
Respiratory protection
Not required.
9. Physical and Chemical Properties
General information
Appearance
Solid white
Odour
Aromatic
pH
Not applicable
Vapour Pressure
<1 hPa
Density
1.2454 g/cm³
Boiling Point
400°C
Melting Point
Undetermined
Solubility
Insoluble
Specific Gravity of Density
Not available
Flash Point
180-190°C
Flammable (Explosive) Limits
Not determined
Ignition Temperature
Not determined
Formula
Not available
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No dangerous decomposition products known.
11. Toxicological Information
Acute effects
No further relevant information available.
Eye contact
Irritating effect.
Skin contact
No irritant effect. Sensitisation possible through skin contact.
Ingestion
No further relevant information available.
Inhalation
No further relevant information available.
Toxicity and irritation
Irritant
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 2: hazardous for water.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13. Disposal Considerations
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
14. Transport Information
ADG label required
Class 1.3 ExplosiveClass 5.2 Organic peroxide
HAZCHEM
No further relevant information available.
UN Number
UN3104
Proper shipping name
3104 ORGANIC PEROXIDE TYPE C, SOLID
Transport hazard class
Class 5.2 Organic peroxides.
Label 5.2±1
Packing group
II
Environmental hazard
Not applicable
Special precautions for users
Warning: Organic peroxides.
EMS Number: F-J,S-R
Stowage category: D
Stowage Code: SW1 Protected from sources of heat.
Segregation Code: SG1 For packages carrying a subsidiary risk of class1, segregation as for class 1, division 1.3. However in relation to goods of class 1, segregation as for the primary hazard.
SG35 Stow 'separated from' SGG1-acids.
SG36 'separated from' SGG18-alkalis.
SG72 See 7.2.6.3.2
Additional information
ADG
Limited quantities (LQ) 100g
Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity.
Transport category: 1
Tunnel restriction code: B
15. Regulatory Information
Poisons Schedule Number
94-36-0 dibenzoyl peroxide S2, S4, S5
Other Information
A Chemical Safety Assessment has not been carried out.
16. Other Information
SDS preparation date
24 February 2026
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.