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Safety Data Sheets / Methanol (Methyl Alcohol)

Safety Data Sheet

Methanol (Methyl Alcohol)

Version 1Last reviewed 25 February 2026Catalogue: 179337, 18510, 18511, CMZ-179305, CMZ-179310, CMZ-179325, EMS18510, EMS18511

1. Identification

Product Identifiers

Product Name
Methanol (Methyl Alcohol)
Other Names
Methyl Alcohol
Product Number(s)
179337, 18510, 18511, CMZ-179305, CMZ-179310, CMZ-179325, EMS18510, EMS18511
CAS Number
67-56-1

Recommended use of the chemical and restriction on use

Laboratory chemicals. For R&D use only. Not for pharmaceutical, household or other uses.

Company Details

ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia
(07) 4773 9444
pst@proscitech.com
proscitech.com.au

Emergency Contact Details

ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia
(07) 4773 9444
pst@proscitech.com
proscitech.com.au

2. Hazards Identification

Classification of the substance or mixture

  • GHS02 Flame
  • Flammable liquids 2 H225 Highly flammable liquid and vapour
  • GHS08 Health Hazard
  • STOT SE 1 H370 Causes damage tot the central nervous system and the visual organs
  • GHS07
  • Acute Tox 4. H302 Harmful if swallowed
  • Acute Tox 4. H312 Harmful in contact with skin
  • Acute Tox 4. H332 Harmful if inhaled

Label Elements

Flammable
Flammable
Harmful / irritant
Harmful / irritant
Health hazard
Health hazard
Signal Words
Danger
Hazard Statement(s)
  • Highly flammable liquid and vapour.
  • Toxic if swallowed, in contact with skin or if inhaled.
  • Causes damage to organs (Eyes, Central nervous system).
Precautionary Statement(s)
  • Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
  • Keep container tightly closed.
  • Ground/bond container and receiving equipment.
  • Use explosion-proof electrical/ventilating/lighting/equipment.
  • Use only non-sparking tools.
  • Take precautionary measures against static discharge.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Wear protective gloves/protective clothing/eye protection/face protection

Primary route(s) of entry

inhalation, ingestion and dermal absorption. Methanol vapours may be inhaled, while liquid methanol can be absorbed through the skin or enter the body through accidental ingestion. Eye contact may also result in exposure.

Human Health

Inhalation
Remove person to fresh air and keep comfortable for breathing.IF exposed: Call a POISON CENTER or doctor/physician.
Ingestion
Call a poison center/doctor if you feel unwell.IF exposed: Call a POISON CENTER or doctor/physician. Rinse mouth.
Eyes
IF exposed: Call a POISON CENTER or doctor/physician.
Skin
Take off immediately all contaminated clothing. Rinse skin with water/shower IF exposed: Call a POISON CENTER or doctor/physician.

Environment

  • Storage:
  • Store in a well-ventilated place. Keep container tightly closed.
  • Store in a well-ventilated place. Keep cool.
  • Store locked up.
  • Disposal:
  • Dispose of contents/ container to an approved waste disposal plant.
  • Dispose of contents/container in accordance with local/regional/national/international regulations.
Other Hazards
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

3. Composition / Information on Ingredients

NameCAS No.Content (w/w)Classification
Methyl Alcohol67-56-1≥ 60 - ≤ 100%Not Available

4. First Aid Measures

Ingestion
Immediately contact the Poisons Information Centre (13 11 26) or seek urgent medical attention. Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Obtain immediate medical attention, even if symptoms are not present, as toxic effects may be delayed. Methanol ingestion may cause severe systemic toxicity, including metabolic acidosis, visual impairment, blindness and potentially death.
Inhalation
  • Supply fresh air or oxygen; call for doctor.
  • In case of unconsciousness place patient stably in side position for transportation
Skin Contact
Immediately wash with water and soap and rinse thoroughly
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor
Other Information
No further relevant information available

5. Firefighting Measures

Suitable extinguishing equipment

Fire
  • CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
  • Hazardous combustion products: Carbon oxides.
HAZCHEM
•2WE

Special protective equipment and precautions for fire fighters

  • Mouth respiratory protective device.
  • Pay attention to flashback.
  • Vapours are heavier than air and may spread along floors.
  • Development of hazardous combustion gases or vapours possible in the event of fire.
  • Forms explosive mixtures with air at ambient temperatures.
  • Specific extinguishing methods: Remove container from danger zone and cool with water.
  • Prevent fire extinguishing water from contaminating surface water or the ground water system.
  • Specific extinguishing methods: Remove container from danger zone and cool with water.
  • Prevent fire extinguishing water from contaminating surface water or the ground water system.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
  • Advice for non-emergency personnel: Do not breathe vapours, aerosols.
  • Avoid substance contact.
  • Ensure adequate ventilation.
  • Keep away from heat and sources of ignition.
  • Evacuate the danger area, observe emergency procedures, consult an expert.
  • Advice for emergency responders: Wear appropriate personal protective equipment, as indicated in Section 8.
Environmental precautions
  • Dilute with plenty of water.
  • Do not allow to enter sewers/ surface or ground water.
  • Risk of explosion.
Methods and materials for containment and clean up
  • Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust
  • Dispose contaminated material as waste according to item 13.
  • Ensure adequate ventilation. Cover drains. Collect, bind, and pump off spills.

7. Handling and Storage

Precautions for safe handling
  • Ensure good ventilation/exhaustion at the workplace.
  • Open and handle receptacle with care.
  • Prevent formation of aerosols.
  • Keep away from open flames, hot surfaces and sources of ignition.
  • Take precautionary measures against static discharge.
Conditions for safe storage
  • Keep receptacle tightly sealed.
  • Store in cool, dry conditions in well sealed receptacles.
  • Keep container tightly closed in a dry and wellventilated place.
  • Keep away from heat and sources of ignition.
  • Keep locked up or in an area accessible only to qualified or authorised persons.
  • Storage class : 3, Flammable liquids
  • Recommended storage temperature: Recommended storage temperature if relevant, see product label.
  • Packaging material: Suitable material: Any Metal Drum

8. Exposure Controls / Personal Protection

Exposure Standards

MaterialTWA ppmTWA mg/m³STEL ppmSTEL mg/m³
Methanol200 ppm262 mg/m3250 ppm328 mg/m3
Engineering controls
No data available.

Personal protective equipment

Eye and face protection
Tightly sealed goggles
Skin protection
Protective gloves
Body protection
Protective clothing
Respiratory protection
  • In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
  • exposure use respiratory protective device that is independent of circulating air

9. Physical and Chemical Properties

General information

Appearance
Colourless fluid
Odour
Alcohol-like
pH
Not determined
Vapour Pressure
128 hPa (96 mm Hg) at 20 °C (68 °F)
Density
0.79 g/cm³ (6.59255 lbs/gal) at 20 °C (68 °F)
Boiling Point
64.7 °C (148.5 °F)
Melting Point
-98 °C (-144.4 °F)
Solubility
Fully miscible.
Specific Gravity of Density
Not determined.
Flash Point
11 °C (51.8 °F)
Flammable (Explosive) Limits
Lower 5.5 Vol %, Upper 44 Vol %
Ignition Temperature
455 °C (851 °F)
Formula
CH3OH

10. Stability and Reactivity

Reactivity
Vapours may form explosive mixture with air.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
  • Risk of explosion with:
  • Oxidizing agents
  • perchloric acid
  • perchlorates
  • salts of oxyhalogenic acids
  • chromium(VI) oxide
  • halogen oxides
  • nitrogen oxides
  • nonmetallic oxides
  • chromosulfuric acid
  • chlorates
  • hydrides
  • zinc diethyl
  • halogens
  • powdered magnesium
  • hydrogen peroxide
  • Nitric acid
  • sulfuric acid
  • permanganic acid
  • sodium hypochlorite
  • Exothermic reaction with:
  • acid halides
  • Acid anhydrides
  • Reducing agents
  • acids
  • Bromine
  • Chlorine
  • Chloroform
  • magnesium
  • tetrachloromethane
  • Risk of ignition or formation of inflammable gases or
  • vapours with:
  • Fluorine
  • Oxides of phosphorus
  • Raney-nickel
  • Generates dangerous gases or fumes in contact with:
  • Alkaline earth metals
  • Alkali metals
Conditions to avoid
Warming.
Incompatible materials
No further relevant information available

11. Toxicological Information

Acute effects
No irritant effect
Eye contact
No irritant effect
Skin contact
No irritant effect
Ingestion
No irritant effect
Inhalation
No irritant effect
Toxicity and irritation
No irritant effect

12. Ecological Information

Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
  • Water hazard class 2 (Assessment by list): hazardous for water
  • Do not allow product to reach ground water, water course or sewage system.
  • Danger to drinking water if even small quantities leak into the ground

13. Disposal Considerations

General information

Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.

14. Transport Information

ADG label required

Class 3 Flammable liquid
Class 3 Flammable liquid
Class 6.1 Toxic
Class 6.1 Toxic
HAZCHEM
•2WE
UN Number
UN1230
Proper shipping name
Methanol
Transport hazard class
3 Flammable liquids
Packing group
II
Environmental hazard
Not applicable.
Special precautions for users
Warning: Flammable liquids
Additional information
not available

15. Regulatory Information

Poisons Schedule Number
313 Specific toxic chemical listings, Hazardous Air Pollutants, Chemicals known to cause developmental toxicity,
Other Information
  • This information is based on our present knowledge. However, this shall not constitute a guarantee for any
  • specific product features and shall not establish a legally valid contractual relationship.

16. Other Information

SDS preparation date
25 February 2026