N,N-Dimethylaniline

1. Identification

Product Identifiers

Product Name

N,N-Dimethylaniline

Other Names

Not available

Product Number(s)

13360, EMS13360

CAS Number

121-69-7

Recommended use of the chemical and restriction on use

Company Details

Emergency Contact Details

2. Hazards Identification

Classification of the substance or mixture

Label Elements

Signal Words

None

Hazard Statement(s)

• Combustible liquid.
• Toxic if swallowed, in contact with skin or if inhaled.
• Suspected of causing cancer.

Precautionary Statement(s)

• Obtain special instructions before use.
• Do not handle until all safety precautions have been read and understood.
• Keep away from flames and hot surfaces. - No smoking.
• Avoid breathing dust/fume/gas/mist/vapours/spray.
• Wash thoroughly after handling.
• Do not eat, drink or smoke when using this product.
• Use only outdoors or in a well-ventilated area.
• Wear protective gloves/protective clothing/eye protection/face protection.

Primary route(s) of entry

Human Health

Inhalation

Remove person to fresh air and keep comfortable for breathing. If exposed or concerned: Get medical advice/attention.

Ingestion

Immediately call a poison centre/doctor. Rinse mouth.

Eyes

Call a poison centre/doctor if you feel unwell.

Skin

Wash with plenty of water. Take off immediately all contaminated clothing and wash it before reuse.

Environment

3. Composition / Information on Ingredients

No information provided.

4. First Aid Measures

Ingestion

Do not induce vomiting; immediately call for medical help.

Inhalation

• Supply fresh air or oxygen; call for doctor.
• In case of unconsciousness place patient stably in side position for transportation.

Skin Contact

Immediately wash with water and soap and rinse thoroughly.

Eye Contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Other Information

• Immediately remove any clothing soiled by the product.
• Remove breathing apparatus only after contaminated clothing have been completely removed.
• In case of irregular breathing or respiratory arrest provide artificial respiration.

5. Firefighting Measures

Suitable extinguishing equipment

Fire

CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

HAZCHEM

No further relevant information available.

Special protective equipment and precautions for fire fighters

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Not required.

Environmental precautions

• Inform respective authorities in case of seepage into water course or sewage system.
• Dilute with plenty of water.
• Do not allow to enter sewers/surface or ground water.

Methods and materials for containment and clean up

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
• Dispose contaminated material as waste according to item 13.
• Ensure adequate ventilation.

7. Handling and Storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.
• Open and handle receptacle with care.
• Keep respiratory protective device available.

Conditions for safe storage

Keep receptacle tightly sealed.

8. Exposure Controls / Personal Protection

Exposure Standards

Engineering controls

• Keep away from foodstuffs, beverages and feed.
• Immediately remove all soiled and contaminated clothing.
• Wash hands before breaks and at the end of work.
• Store protective clothing separately.
• Avoid contact with the eyes and skin.

Personal protective equipment

Eye and face protection

Goggles recommended during refilling.

Skin protection

Wear protective clothing.

Body protection

Protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Respiratory protection

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.

9. Physical and Chemical Properties

General information

Appearance

Light yellow liquid

Odour

Characteristic

pH

7.4

Vapour Pressure

1hPa at 30°C

Density

0.956g/cm³ at 20°C

Boiling Point

193°C

Melting Point

1.5°C

Solubility

Fully miscible

Specific Gravity of Density

Not available

Flash Point

75°C

Flammable (Explosive) Limits

• Lower: 1 Vol%
• Upper: 7 Vol%

Ignition Temperature

370°C

Formula

C₆H₅N(CH₃)₂

10. Stability and Reactivity

Reactivity

No further relevant information available.

Chemical stability

No decomposition if used according to specifications.

Possibility of hazardous reactions

No dangerous reactions known.

Conditions to avoid

No further relevant information available.

Incompatible materials

No further relevant information available.

11. Toxicological Information

Acute effects

• Oral LD50 1410 mg/kg (rat)
• Dermal LD50 1770 mg/kg (rabbit)

Eye contact

No irritating effect.

Skin contact

No irritant effect.

Ingestion

Not available.

Inhalation

No sensitizing effects known.

Toxicity and irritation

Not available.

12. Ecological Information

Ecotoxicity

Toxic for fish.

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Other adverse effects

• Water hazard class 3: extremely hazardous for water.
• Do not allow product to reach ground water, water course or sewage system, even in small quantities.
• Danger to drinking water if even small quantities leak into the ground.
• Also poisonous for fish and plankton in water bodies.
• Toxi for aquatic organisms.

13. Disposal Considerations

General information

14. Transport Information

ADG label required

HAZCHEM

No further relevant information available.

UN Number

UN2253

Proper shipping name

2253 N,N-DIMETHYLANILINE, ENVIRONMENTALLY HAZARDOUS

Transport hazard class

Class 6.1 Toxic substances

Packing group

II

Environmental hazard

• Environmentally hazardous substance, liquid; Marine Pollutant
• Marine pollutant: Yes (DOT)
• Symbol (fish and tree)

Special precautions for users

• Warning: Toxic substances
• Hazard identification number (Kemler code): 60
• EMS Number: F-A,S-A
• Stowage Category: A

Additional information

• DOT
• Quantity limitation:
• On passenger aircraft/rail: 5L
• On cargo aircraft only: 60L
• Hazardous substance: 100lbs, 45.4kg
• Special marking with the symbol (fish and tree)
• ADR
• Excepted quantities (EQ) Code: E4
• Maximum net quantity per inner packaging: 1mL
• Maximum net quantity per outer packaging: 500mL
• IMDG
• Limited quantities (LQ) 100mL
• Excepted quantities (EQ) Code: E4
• Maximum net quantity per inner packaging: 1mL
• Maximum net quantity per outer packaging: 500ml

15. Regulatory Information

Poisons Schedule Number

Substance is not listed.

Other Information

A Chemical Safety Assessment has not been carried out.

16. Other Information

SDS preparation date

24 February 2026

Comments

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.