Do not allow to enter sewers/ surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
108-88-3 Toluene
WEL: Short-term value: 384 mg/m³, 100 ppmLong
-
-
-
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles recommended
Skin protection
Gloves recommended
Body protection
Protective clothing recommended
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. Physical and Chemical Properties
General information
Appearance
Yellow liquid
Odour
Characteristic
pH
Not determined.
Vapour Pressure
29 hPa at 20°C
Density
1.79372 g/cm³ at 20°C
Boiling Point
110°C
Melting Point
Undetermined.
Solubility
Not miscible or difficult to mix.
Specific Gravity of Density
Not available.
Flash Point
7°C
Flammable (Explosive) Limits
Not applicable. Product is not selfigniting. Product is not explosive. However, formation of explosive air/vapour
mixtures are possible. Explosion limits:
Lower: 1.2 Vol %
Upper: 7.0 Vol %
Ignition Temperature
535 °C
Formula
Not available.
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
Not available.
Possibility of hazardous reactions
No further relevant information available.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
No further relevant information available.
Eye contact
Irritating effect.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
No further relevant information available.
Inhalation
No further relevant information available.
Toxicity and irritation
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13. Disposal Considerations
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations.
Special precautions for user Warning: Flammable liquids.
Danger code (Kemler): 33
EMS Number: F-E,S-E
Additional information
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
ADR
Limited quantities (LQ) 0
Excepted quantities (EQ) Code: E3
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 300 mL
Transport category 1
Tunnel restriction code D/E
IMDG
Limited quantities (LQ) 0
Excepted quantities (EQ) Code: E3
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 300 ml
15. Regulatory Information
Poisons Schedule Number
A Chemical Safety Assessment has not been car
Other Information
No further relevant information available.
16. Other Information
SDS preparation date
11 March 2020
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.