Remove victim to fresh air and keep at rest in a position comfortable for breathing. If exposed or concerned: Get medical advice/attention.
Ingestion
Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Eyes
Not available.
Skin
(or hair) remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. Brush off loose particles from skin. Immerse in cool water/wrap in bandages.
Environment
In case of fire: Use CO₂, sand, extinguishing powder for extinction.
Store in a dry place. Store in a closed container.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / Information on Ingredients
Name
CAS No.
Content (w/w)
Classification
Methyl Methacrylate
80-62-6
>50-≤100%
Mixture
N,N-dimethyl-p-toluidine
99-97-8
>2.5-≤10%
Mixture
4. First Aid Measures
Ingestion
Do not induce vomiting; call for medical help immediately.
Inhalation
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
5. Firefighting Measures
Suitable extinguishing equipment
Fire
CO, sand, extinguishing powder. Do not use water.
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
Special protective equipment and precautions for fire fighters
Mouth respiratory protective device.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
7. Handling and Storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage
Store in a cool location.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8. Exposure Controls / Personal Protection
Exposure Standards
Material
TWA ppm
TWA mg/m³
STEL ppm
STEL mg/m³
Methyl Methacrylate
50ppm
208mg/m³
100ppm
406mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Avoid contact with the skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Wear protective gloves. The glove material has to be impermeable to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times. rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Not available.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. Physical and Chemical Properties
General information
Appearance
Yellowish fluid
Odour
Characteristic
pH
Not determined
Vapour Pressure
47hPa
Density
0.94482g/cm³
Boiling Point
>35°C
Melting Point
-48°C
Solubility
1.6g/l
Specific Gravity of Density
Not available.
Flash Point
10°C
Flammable (Explosive) Limits
Lower: 2.1Vol%
Upper: 12.5Vol%
Ignition Temperature
430°C
Formula
Not available.
10. Stability and Reactivity
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
Contact with water releases flammable gases.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. Toxicological Information
Acute effects
80-62-6 Methyl Methacrylate
Oral LD50 7872mg/kg (rat)
Eye contact
No irritating effect.
Skin contact
Irritant to skin and mucous membranes. Sensitisation possible through skin contact.
Ingestion
Not available
Inhalation
Not available
Toxicity and irritation
Toxic
Irritant
12. Ecological Information
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 1: slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13. Disposal Considerations
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
14. Transport Information
ADG label required
Class 3 Flammable liquid
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
UN Number
UN1247
Proper shipping name
1247 METHYL METHACRYLATE MONOMER, STABILIZED
Transport hazard class
Class 3 Flammable liquids
Packing group
II
Environmental hazard
Not applicable.
Special precautions for users
Warning: Flammable liquids
Hazard identification number (Kemler code): 33
EMS Number: F-E,S-D
Stowage Category: B
Stowage code: SW2 Clear of living quarters.
Additional information
Limited quantities (LQ): 1L
Excepted quantities (EQ): Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category: 2
Tunnel restriction code: D/E
15. Regulatory Information
Poisons Schedule Number
80-62-6 Methyl Methacrylate S6, S10
Other Information
A Chemical Safety Assessment has not been carried out.
16. Other Information
SDS preparation date
1 March 2026
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific features and shall not establish a legally valid contractual relationship.